Product ID:CPS201110, UNLEADED GASOLINE
MSDS Date:07/03/1989
FSC:9130
NIIN:00N018990
MSDS Number: BNNNF

CHEVRON ENVIRONMENTAL HEALTH CENTER

15299 SAN PABLO AVE.
RICHMOND, CA 94804-0054
US

Emergency Phone: 415-233-3737 OR 800-457-2022

Info Phone: 415-233-3737

Cage: 0AHD1

CHEVRON ENVIRONMENTAL HEALTH CENTER INC

4054 RICHMOND, CA 94804 US

Telephone: 800-582-3835

Cage: 0AHD1

PERS VOMIT UNLESS DIRECTED TO DO SO BY MED PERS. IF

RTECS: 9999999ZZ

CNTNR TO NEAREST MED EMER TREATMENT

RTECS: 9999999ZZ

IN ASPIRATION OF LIGHT HYDROCARBON LIQUID WHICH CAN

RTECS: 9999999ZZ

WHERE FEASIBLE & APPROP, REMOVE CONTAMD SOIL.

RTECS: 9999999ZZ

LARGER RELEASES.

RTECS: 9999999ZZ

GIVE

RTECS: 9999999ZZ

M-XYLENE

CAS: 108-38-3

RTECS: ZE2275000

Fraction By Weight: <4.6%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;15O PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <6.5%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE; (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CYCLOHEXANE

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: <2.4%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHER, TERT-BUTYL METHYL; (METHYL TERT-BUTYL ETHER)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BENZENE

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <4.9%

OSHA PEL 1 PPM;5 PPM STEL

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

O-XYLENE

CAS: 95-47-6

RTECS: ZE2450000

Fraction By Weight: <2.2%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

INTENTIONAL EXPOSURES TO EXCESSIVELY HIGH

RTECS: 9999999ZZ

SLIGHTLY TOX TO

RTECS: 9999999ZZ

DIZZ, LOSS OF APPETITE, WEAKNESS & LOSS OF

RTECS: 9999999ZZ

(THIS IS CALLED ASPIRATION). CAN CAUSE SEVERE

RTECS: 9999999ZZ

RPTD/PRLNGD BRTHG OF BENZENE VAPS HAS BEEN ASSOCD

RTECS: 9999999ZZ

APLASTIC ANEMIA TO LEUKEMIA (A FORM OF CANCER).

RTECS: 9999999ZZ

W/N-HEXANE MAY CAUSE NERVE DAM CHARACTERIZED BY

RTECS: 9999999ZZ

DEEP TENDON REFLEXES AND REDUCTION OF MOTOR NERVE

RTECS: 9999999ZZ

P-XYLENE

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: <0.9%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CHRONIC ABUSERS (GLUE SNIFFERS/SOLV HUFFERS) OF

RTECS: 9999999ZZ

GASOLINE; (GASOLINE, UNLEADED CONSISTING OF INGREDIENTS

RTECS: LX3373000

Fraction By Weight: 100%

OSHA PEL 300 PPM;500 PPM STEL

ACGIH TLV: 300 PPM;500 PPM STEL

BENZENE, ETHYL-; (ETHYL BENZENE)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <1.4%

OSHA PEL 100 PPM;125 PPM STEL

ACGIH TLV: 100 PPM;125 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50: (ORAL, RAT) 18.75 ML/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE: SLIGHTLY IRRITATING & COULD CAUSE
PRLNGD (DAYS) IMPAIRMENT OF VISION. SIGNS & SYMPS MAY INCLUDE PAIN,
TEARS, SWELLING, REDNESS, & BLURRED VISION. SKIN: PRLNGD/FREQUENTLY
RPTD CONT MAY CAUSE SKIN TO BECOME CRACKED/DRY FROM DEFAT ACTION.
IF ABSORBED THRU SKIN, PRACTICALLY NON-TOX. INHAL: SLIGHTLY (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: KNOWM CARCINOGEN (NTP), GROUP 1
(IARC), OSHA-REGULATED; UNLEADED GASOLINE (IARC) GROUP 2B.
Effects of Overexposure:HLTH HAZ:TOX TO INTERNAL ORGANS IF INHALED.
TARGET ORGAN IS THE NERVOUS SYS. EXCEEDING 100 PPM MAY CAUSE SIGNS
& SYMPTOMS OF CNS EFTS SUCH AS HDCH, DIZZ, LOSS OF APPETITE,
WEAKNESS & LOSS OF COORDINAT ION. VAP >5000 PPM MAY CAUSE LOSS OF
CONSCIOUSNESS, COMA & DEATH, PULMONARY EDEMA & BRONCHITIS. (ING 11)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: FLUSH IMMED W/FRESH WATER FOR @ LST 15 MIN WHILE HOLDING
LIDS OPEN. REMOVE CONT LENSES IF WORN. NO ADDITIONAL FIRST AID SHLD
BE NEC HOWEVER, IF IRRIT PERSISTS, SEE MD. SKIN: REMOVE CONTAMD
CLTHG. WASH THORO W/SOAP & WATER. SEE MD IF ANY SIGNS/SYMPS
DESCRIBED IN MSDS OCCUR. DISCARD CONTAMD NON-WATERPROOF SHOES &
BOOTS. WASH CONTAMD CLTHG. INHAL: MOVE TO FRESH AIR. IF ANY OF
THESE (ING 20)

Flash Point Method:PMCC
Flash Point:<-49F,<-45C
Lower Limits:1.4%
Upper Limits:7.6%
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM AND WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. PRESENTS AN EXTREME FIRE HAZ. LIQ VERY QUICKLY EVAPORATES, EVEN @
LOW TEMPS, & FORMS VAP (SUPP DATA)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:PROD SHLD BE PVNTD FROM CONTAMINATING SOIL &
WATER & FROM ENTERING DRAINAGE & SEWER SYS. ELIM ALL IGNIT SOURCES
IN VICINITY OF SPILL/RELEASED VAP. CLEAN UP SM SPILLS USING APPROP
TECHNIQUES SUCH AS SO RBENT MATLS/PUMPING. (ING 24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR CLSD.DO NOT TRANSFER LIQ TO
AN UNLABELED CNTNR. REPLACE CAP OR BUNG. EMPTIED CNTNR STILL
CONTAINS HAZ OR EXPLOSIVE VAP/LIQ.EXTREMELY FLAMM.
Other Precautions:NEVER SIPHON GASOLINE BY MOUTH. READ & OBSERVE ALL
PRECS ON PROD LABEL. USE ONLY AS MOTOR FUEL. DO NOT USE/STORE NEAR
FLAME, SPKS/HOT SURFS. USE ONLY IN WELL VENTD AREA. DO NOT WELD,
HEAT/DRILL CNTNR. KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:NO SPECIAL RESP PROTECTION IS NORMALLY REQUIRED.
IF OPERATING CONDITIONS CREATE AIRBORNE CONCENTRATIONS WHICH EXCEED
THE RECOMMENDED EXPOSURE STANDARDS, THE USE OF A NIOSH/MSHA
APPROVED RESPIRATOR IS REQUIRED.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:REFER TO OSHA BENZENE STANDARD (29 CFR
1910.1028).
Supplemental Safety and Health
VP: 5-15PSI (MAX) @ 100F (VARIABLE). FIRE FIGHT PROC: (FUMES) WHICH CAN
CATCH FIRE & BURN W/EXPOSIVE VIOLENCE. INVISIBLE VAP SPREADS EASILY
& CAN BE SET ON FIRE BY MANY SOURCES SUCH AS PILOT LIGHTS, W ELDING
EQUIP & ELEC MOTORS & SWITCHES.

HCC:F2
Boiling Pt:B.P. Text:>77F,>25C
Vapor Pres:SUPP DATA
Vapor Density:3-4
Spec Gravity:0.7-0.8
Solubility in Water:INSOLUBLE
Appearance and Odor:ORANGE TO BRONZE LIQUID.
Percent Volatiles by Volume:99+

Stability Indicator/Materials to Avoid:YES
MAY REACT WITH STRONG OXIDIZING AGENTS, SUCH AS CHLORATES, NITRATES,
PEROXIDES, ETC.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY COMBUST:NORM COMBUST FORMS CO*2 &
WATER VAP; INCOMPLETE COMBUST CAN PRDCE CO.

Waste Disposal Methods:PLACE CONTAMD MATLS IN DISPOSABLE CONTAINERS AND
DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE REGULATIONS.
CONTACT LOCAL ENVIRONMENTAL OR HEALTH AUTHORITIES FOR APPROVED
DISPOSAL OF THIS MATERIAL . DISPOSE I/A/W FED, STATE & LOC REGS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.